Product ID:AA 3-007
MSDS Date:01/26/1998
FSC:8010
NIIN:01-441-5940
Status Code:A
MSDS Number: CLMHR

ASHLAND CHEMICAL CO

COLUMBUS, OH 43216-2219
US

Emergency Phone: 1-800-274-5263

Info Phone: 614-790-3333/800-274-5263

Preparer: ERNEST CARTER

Cage: 34897

ASHLAND CHEMICAL CO

2219 COLUMBUS, OH 43216-2219 US

Telephone: 614-790-3333/800-274-5263

Cage: 34897

ALIPHATIC PETROLEUM DISTILLATES

CAS: 64742-89-8

ISOBUTYL ISOBUTYRATE

CAS: 97-85-8

RTECS: NQ5250000

ISOPROPANOL

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 980 MG/M3;400 PPM

ACGIH TLV: 983 MG/M3;400 PPM

ETHYL ACETATE

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 1400 MG/M3;400 PPM

ACGIH TLV: 1440 MG/M3;400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE: SYMPTOMS INCLUDE STINGING,
TEARING, REDNESS, AND SWELLING OF EYES. SKIN: SYMPTOMS MAY INCLUDE
REDNESS, BURNING, DRYING AND CRACKING OF SKIN, AND SKIN BURNS.
SWALLOWING: LARGE AMOUNTS MAY BE HAR MFUL. THIS MATERIAL CAN GET
INTO THE LUNGS DURING SWALLOWING OR VOMITING. INHALATION:
BREATHING LARGE AMOUNTS MAY BE HARMFUL. SYMPTOMS USUALLY OCCUR AT
AIR CONCENTRATIONS HIGHER THAN THE RECOMMENDED EXPOSURE LIMITS.
Effects of Overexposure:SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL
THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THIS MATERIAL
THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET, NAUSEA,
VOMITING, DIARRHEA, IR RITATION, (NOSE, THROAT, AIRWAYS), CENTRAL
NERVOUS SYSTEM DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS), LOW BLOOD PRESSURE,
MILD TEMPORARY CHANGES IN THE LI VER, EFFECTS ON HEART RATE,
RESPIRATORY DEPRESSION, (SLOWING OF BREATHING), LOSS OF
COORDINATION, CONFUSION, LUNG EDEMA (FLUID BUILDUP IN THE LUNG
TISSUE) KIDNEY DAMAGE AND COMA.
Medical Cond Aggravated by Exposure:MATERIAL IS ASPIRATION HAZARD.
DANGER FROM ASPIRATION MUST BE WEIGHED AGAINST ORAL TOXICITY WHEN
DECIDING WHETHER TO INDUCE VOMITING.

First Aid:EYES: MOVE PERSON AWAY TO FRESH AIR. FLUSH GENTLY WITH WATER
AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER.
LAUNDER CLOTHIN G. SWALLOWING: IF INDIVIDUAL IS DROWSY OR
UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH. PLACE PERSON ON LEFT
SIDE WITH THE HEAD DOWN. INHALATION: MOVE PERSON INTO FRESH AIR. IF
BREATHING IS DIFFICULT, A DMINISTER OXYGEN. KEEP PERSON WARM AND
QUIET.

Flash Point Method:TCC
Flash Point:=10.C, 50.F
Lower Limits:1.0%
Upper Limits:12.0%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE
WITH APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED
BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC
MOTORS, STATIC DISCHARGE, OR OT HER IGNITION SOURCES AT LOCATIONS.
NEVER USE WELDING TORCH NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT CAN
IGNITE EXPLOSIVELY

Spill Release Procedures:ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT.
LARGE SPILL: ELIMINATE IGNITION SOURCES (FLARES, FLAMES INCLUDING
PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE
EQUIPMENT SHOULD BE EX CLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS
BEEN COMPLETED. STOP SPILL AT SOURCE. PREVENT FROM ENTERING DRAINS,
SEWERS, STREAMS, OR OTHER WATER BODIES. PREVENT FROM SPREADING.
ABSORB UNRECOVERABLE PR

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS
GIVEN IN THE DATA SHEET MUST BE OBSERV ED. ALL 5 GALLON PAILS AND
LARGER METAL CONTAINERS, INCLUDING TANK CARS AND TANK TRUCKS SHOULD
BE GR

Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS OF PRODUCT OR ANY
COMPONENT IS EXCEEDED (SEE EXPOSURE GUIDELINES) A NIOSH/MSHA
APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV?S.
Protective Gloves:WEAR RESISTANT GLOVES.
Eye Protection:CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA
REGULATIONS ARE ADVISED)
Other Protective Equipment:IMPREVIOUS CLOTHING AND BOOTS.
Supplemental Safety and Health

Boiling Pt:=75.6C, 168.F
Vapor Pres:76.000 MMHG @ 58.00 F
Vapor Density:.1, AIR=1
Spec Gravity:[email protected] F
VOC Pounds/Gallon:782
VOC Grams/Liter:6.51
Evaporation Rate & Reference:SLOWER THAN ETHYL

Stability Indicator/Materials to Avoid:YES
ACETALDEHYDE, ACIDS, CHLORINE, ETHYLENE OXIDE ISOCYANATES, STRONG
ALKALIES, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT USE WITH ALUMINUM EQUIPMENT AT
TEMPERATURES ABOVE 120 F
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE,
VARIOUS HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

Toxicological Information:SILICON: LD50 (ORAL, RAT) 3160 MG/KG.
MANGANESE: LD50 (ORAL, RAT) 9,000 MG/KG. IRON: INTRAPERITONEAL
RABBIT LDL0: 20 MG/KG - NO TOXIC EFFECT NOTED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT AVAILABLE

Transport Information:CONTAINER/MODE: 55 GAL DRUM/TRUCK PACKAGE NOS
COMPONENT: NOT APPLICABLE RQ (REPORTABLE QUANTITY) -49 CFR 172.101
PRODUCT QUANTITY: (50000 LBS) COMPONENT: BENZENE

Federal Regulatory Information:CERCLA RQ: ETHYL ACETATE: 5000 LB RQ;
State Regulatory Information:CALIFORNIA CARCINOGENS: BENZENE,
ACETALDEHYDE; NJ RIGHT TO KNOW: NAPHTHA, SOLVENT, 64742-89-8,
ISOBUTYL ISOBUTYRATE, 97-85-8, ISOPROPYL ALCOHOL, 67-63-0, ETHYL
ACETATE, 141-78-6; PA RIGHT TO KNOW: AL IPHATIC PETROLEUM
DISTILLATES: 64742-89-8, 2-PROPANOL: 67-63-0, ACETIC ACID ETHYL
ESTER: 141-78-6